Tag Archives: resina epoxi

CIPP – where do we go from here?

Cured-in-place pipe (CIPP) appears with hindsight as one of the most significant breakthroughs of the last century. Some 50,000 km of cured-in-place pipe has been installed worldwide since 1971. For 20 years

the technology was protected by substantial patents and licensing policies. The tight grip relaxed in the 1990s and vigorous competition ensued as new processes and materials were introduced.

These developments have strengthened the cured-in-place pipe (CIPP) brand, but inevitably the technology has suffered from commoditisation of the process. Products are no longer differentiated on brand, design or quality, and are bought solely on price. In this process, a common phenomenon as markets mature, prices come under pressure, profit margins shrink and R&D and customer service are sacrificed.

Licensing was central to the CIPP business. Use of patents and know-how were regulated by exclusive agreements in defined geographical territory. Licensees received initial training and technical support from licensors who managed the supply of materials and equipment. Close support included assistance from skilled installers. Exchange of experience and continuous improvement was beneficial, serving pipeline owners well, maintaining knowledge and standards.

However, over time, commoditisation fragments know-how and technology enhancement. As licensed networks break up, technical controls must be put in place by pipeline owners and industry regulatory bodies to maintain standards. The process of regulation typically evolves from proprietary manuals through industry codes to international standards. In the case of CIPP, the WRc 4-34-04 specification strongly influenced the development of BS EN 13566, now replaced by ISO 11296.

The first CIPP installation involved pulling into place a polyester impregnated felt liner, inflating and leaving to cure at ambient temperature. With improved materials this evolved into the familiar water inversion and heat cure process. Air inversion and steam curing took CIPP into water and gas mains. In 1985, UV methods were launched. Commercial pressures saw the use of fillers or resin extenders to improve flexural elastic modulus and heat transfer, as well as reduce cost. Awareness of infiltration through the joints in house connections led to lateral lining methods. Market demand, particularly in North America, and the expiry of original patents stimulated growth, and new faces entered the marketplace.

The growth in demand has encouraged an increase in liner and resin manufacture and distribution by companies, beginning a progression towards commoditisation leading to distribution of materials and equipment through merchants and hire firms with limited technical support. Small diameter installation by pulling in, inflation and ambient cure is less demanding than inversion and heat cure with regulated installation pressures, curing and cooling cycles and precise mixing equipment.

More recently, glass fabric linings installed by air inversion and cured with steam and UV has grown popular for gravity and pressure. In Germany, glass fibre liners make up 63 per cent of liners installed, and UV curing methods are used in Europe for 40 per cent of liners. Vinyl Ester and epoxy resins are employed for extra chemical and temperature resistance; epoxies are used for potable water linings. However, polyester resin is preferred for the sewer rehabilitation, where market share is still thought to be 90 per cent. The private sewer market, growing strongly, uses epoxy resin and silicate resins.

There is a debate about the hazards involved in the use of resins. Styrene, a major constituent in polyesters, is classified in Europe as ‘possibly carcinogenic’. The UK HSE, working for the European Union, has concluded there is no clear evidence of a causal link between styrene and cancer mortality. Recently, the US Department of Health and Human Services reclassified Styrene as a ‘reasonably anticipated carcinogen’. The American Composite Manufacturers Association contests this, but in the meantime industry professionals have to determine how best to respond.

Epoxies, though not listed as carcinogenic, are cited as very toxic, requiring careful handling. These polymers are hazardous on skin contact and dangerous if inhaled, so precautions must be taken to protect installation workers who can become sensitised after repeated exposure. The public are sensitive to odours; styrene in particular is detectable in low doses, and epoxies have a characteristic smell which can also raise concerns. Contractors must take steps to safeguard the public and demonstrate compliance with health and safety requirements.

Polymer resins shrink on curing. Crosslinking, the process which generates strength and stiffness, and cooling both involve a volume reduction. The extent depends upon resin type, curing temperature, reinforcements and fillers. Measurements of shrinkage for neat polyester are typically 6–7 per cent whereas epoxy resins exhibit 2–3 per cent.

Does it matter? There are mitigating factors; mechanical or chemical bonding restricts shrinkage and the installation pressure expands the hot plastic pipe to restore the close fit, counteracting shrinkage. Whilst it is easy enough to demonstrate in the laboratory, the real problems may be minimal if the liner is properly installed.

The issue has become a talking point used to promote one material over another. However, it is more important to focus on real issues: laterals and their joints, with the sewer main, are responsible for 50 per cent of the infiltration. Effort is better invested in sealing the system than bickering about the resin. The challenge is to develop methods with improved productivity and lower costs. This may find a fruitful testing ground in the UK with the addition of 200,000 km of private sewers to the network, and the introduction of new service standards by the Water Services Regulation Authority.

Installation failures are rare where installers are properly trained and owners supervise workmanship. International standards like ISO11296 and corresponding ASTM documents can inform quality contract specifications. Many call for trained engineers and installers — admirable sentiments, but little training is available. We need good courses in CIPP and education for engineers to understand installation and quality issues. The ‘out of sight, out of mind’ nature of the industry lends itself to mismanagement, unless contractors and owners take good practice and quality to heart.

The IKT Report has driven the popularity of glass-reinforced liners in Europe. It details performance in tests of modulus, strength, thickness and impermeability to establish liner fitness for purpose. The reports, published since 2003, provide owners with facts about compliance with standards. The drive for improvement is leading suppliers to focus on materials. Progress is being made in the US to develop resins. Sustainable low emission products are expensive but they will close the price gap with increased use. Reinforcing fibres provide a greater proportion of product performance and lower resin usage minimises chemical issues. Providers constantly strive to reduce costs, moving from hot water to steam, and UV cure can cut hours off installation times. Owners can develop efficiencies by encouraging innovation, releasing work in packages, allowing contractors to best use resources.

Thermoplastics may be another alternative. The Aqualiner process developed with three UK WASCs has WRc Approval and meets NSF61 for contact with potable water. Licensed to OnSite Central, Aqualiner had its first commercial outing at Portland for Wessex Water in 2010. The glass and polypropylene composite has no hazardous constituents and a long life. The thermoplastic provides the opportunity for welded joints and easy maintenance. The liner exhibits a tight fit, high strength, good abrasion and chemical resistance. This development is perhaps the next generation in the ongoing story of CIPP linings.

The first CIPP installation involved pulling into place a polyester-impregnated felt liner, inflating and leaving to cure at ambient temperature.

Dr Dec Downey, Trenchless opportunities ltd
Featured in January 2012

http://trenchlessinternational.com/news/cipp_where_do_we_go_from_here/065224/

 

Resina de Poliéster y Epoxy DIFERENCIAS

¿Cuáles son las principales diferencias entre las resinas de poliéster y las resinas epoxi?

El 75% de las resinas utilizadas por sus usuarios son resinas poliéster no saturadas (los usos para las resinas de poliéster saturadas se limitan al revestimiento), las resinas epoxi se muestran mejores por su fiabilidad. Aunque ambas resinas responden bien sobre y bajo el agua, epoxi resiste completamente la humedad, mientras que la poliéster no lo hace.

Conocer las propiedades, ventajas y limitaciones de estos dos agentes adhesivos puede ayudar a elegir el más adecuado para cada proyecto.

MANGA CONTINUA

MANGA CONTINUA

Las resinas de poliéster son resinas que se hacen reaccionar con catalizadores de tipo peróxido orgánico en pequeñas proporciones (1-2,5%) para que puedan endurecer, mientras que las resinas epoxi precisan de endurecedores (normalmente aminas) en la relaciones de mezcla normalmente superiores.
Las resinas de poliéster de tipo insaturado empleadas para la fabricacion de composites con fibras de refuerzo (fundamentalmente de vidrio) tienen altos contenidos de disolvente (estireno), parte del cual reacciona con el polímero y endurece, formando parte de la estructura sólida de la resina. Pero un cierto contenido se evapora, dando a estas resinas un olor característico en la fase estática y dinámica de los procesos de fabricación. Esta evaporación conduce a una contracción que oscila entre el 6 y el 8% en volumen según los tipos de resinas de poliéster.
Sin embargo, las resinas epoxi presenta una muy baja contracción y por eso son más empleadas en procesos en los que las tolerancias sean más exigentes.

Las resinas epoxi tienen una gran capacidad para unir materiales de diferente naturaleza y ya curados. Las resinas polyester tienen un poder de adherencia más pobre. Las resinas epoxi de gran calidad tienen una resistencia de adherencia de 2.000 psi (13,8 MPa) frente a la resina polyester con 100 psi (0,7 MPa).

Las resinas de poliéster son generalmente más fluidas que las resinas epoxi.

Epoxi es superior a las resinas poliéster por su resistencia a líquidos y lugares ácidos. Con sus mejores propiedades eléctricas, inmejorable rendimiento a altas temperaturas y su capacidad para adherirse a múltiples tipos de superficies, la resina epoxi de nuevo supera a la poliéster.

Por último, las resinas de poliéster son más baratas que las epoxi y de ahí su mayor presencia en el mercado en términos de volumen.

IMPREGNACION RESINA EPOXI IN SITUFase impregnación manga continua en obra

AST Grupo emplea en la mayoría de los procesos de rehabilitación interior de tuberías con manga continua (CIPP) resina epoxi bicomponente de alta calidad.

RESINA EPOXY

http://www.ibermutuamur.es/revista_bip_antigua/20/pdf/seguridadlaboral_bip20.pdf

http://www.ehowenespanol.com/resina-poliester-frente-resina-epoxi-sobre_10539/

Resinas Castro tienda virtual.